68 research outputs found
Local influence of boundary conditions on a confined supercooled colloidal liquid
We study confined colloidal suspensions as a model system which approximates
the behavior of confined small molecule glass-formers. Dense colloidal
suspensions become glassier when confined between parallel glass plates. We use
confocal microscopy to study the motion of confined colloidal particles. In
particular, we examine the influence particles stuck to the glass plates have
on nearby free particles. Confinement appears to be the primary influence
slowing free particle motion, and proximity to stuck particles causes a
secondary reduction in the mobility of free particles. Overall, particle
mobility is fairly constant across the width of the sample chamber, but a
strong asymmetry in boundary conditions results in a slight gradient of
particle mobility.Comment: For conference proceedings, "Dynamics in Confinement", Grenoble,
March 201
On the study of jamming percolation
We investigate kinetically constrained models of glassy transitions, and
determine which model characteristics are crucial in allowing a rigorous proof
that such models have discontinuous transitions with faster than power law
diverging length and time scales. The models we investigate have constraints
similar to that of the knights model, introduced by Toninelli, Biroli, and
Fisher (TBF), but differing neighbor relations. We find that such knights-like
models, otherwise known as models of jamming percolation, need a ``No Parallel
Crossing'' rule for the TBF proof of a glassy transition to be valid.
Furthermore, most knight-like models fail a ``No Perpendicular Crossing''
requirement, and thus need modification to be made rigorous. We also show how
the ``No Parallel Crossing'' requirement can be used to evaluate the provable
glassiness of other correlated percolation models, by looking at models with
more stable directions than the knights model. Finally, we show that the TBF
proof does not generalize in any straightforward fashion for three-dimensional
versions of the knights-like models.Comment: 13 pages, 18 figures; Spiral model does satisfy property
Self-Similarity in Random Collision Processes
Kinetics of collision processes with linear mixing rules are investigated
analytically. The velocity distribution becomes self-similar in the long time
limit and the similarity functions have algebraic or stretched exponential
tails. The characteristic exponents are roots of transcendental equations and
vary continuously with the mixing parameters. In the presence of conservation
laws, the velocity distributions become universal.Comment: 4 pages, 4 figure
Anomalous Diffusion in Infinite Horizon Billiards
We consider the long time dependence for the moments of displacement < |r|^q
> of infinite horizon billiards, given a bounded initial distribution of
particles. For a variety of billiard models we find ~ t^g(q) (up to
factors of log t). The time exponent, g(q), is piecewise linear and equal to
q/2 for q2. We discuss the lack of dependence of this result
on the initial distribution of particles and resolve apparent discrepancies
between this time dependence and a prior result. The lack of dependence on
initial distribution follows from a remarkable scaling result that we obtain
for the time evolution of the distribution function of the angle of a
particle's velocity vector.Comment: 11 pages, 7 figures Submitted to Physical Review
Glassy dynamics in granular compaction: sand on random graphs
We discuss the use of a ferromagnetic spin model on a random graph to model
granular compaction. A multi-spin interaction is used to capture the
competition between local and global satisfaction of constraints characteristic
for geometric frustration. We define an athermal dynamics designed to model
repeated taps of a given strength. Amplitude cycling and the effect of
permanently constraining a subset of the spins at a given amplitude is
discussed. Finally we check the validity of Edwards' hypothesis for the
athermal tapping dynamics.Comment: 13 pages Revtex, minor changes, to appear in PR
Structural Probe of a Glass Forming Liquid: Generalized Compressibility
We introduce a new quantity to probe the glass transition. This quantity is a
linear generalized compressibility which depends solely on the positions of the
particles. We have performed a molecular dynamics simulation on a glass forming
liquid consisting of a two component mixture of soft spheres in three
dimensions. As the temperature is lowered (or as the density is increased), the
generalized compressibility drops sharply at the glass transition, with the
drop becoming more and more abrupt as the measurement time increases. At our
longest measurement times, the drop occurs approximately at the mode coupling
temperature . The drop in the linear generalized compressibility occurs at
the same temperature as the peak in the specific heat. By examining the
inherent structure energy as a function of temperature, we find that our
results are consistent with the kinetic view of the glass transition in which
the system falls out of equilibrium. We find no size dependence and no evidence
for a second order phase transition though this does not exclude the
possibility of a phase transition below the observed glass transition
temperature. We discuss the relation between the linear generalized
compressibility and the ordinary isothermal compressibility as well as the
static structure factor.Comment: 18 pages, Latex, 26 encapsulated postscript figures, revised paper is
shorter, to appear in Phys. Rev.
Thermal noise properties of two aging materials
In this lecture we review several aspects of the thermal noise properties in
two aging materials: a polymer and a colloidal glass.
The measurements have been performed after a quench for the polymer and
during the transition from a fluid-like to a solid-like state for the gel. Two
kind of noise has been measured: the electrical noise and the mechanical noise.
For both materials we have observed that the electric noise is characterized
by a strong intermittency, which induces a large violation of the Fluctuation
Dissipation Theorem (FDT) during the aging time, and may persist for several
hours at low frequency. The statistics of these intermittent signals and their
dependance on the quench speed for the polymer or on sample concentration for
the gel are studied. The results are in a qualitative agreement with recent
models of aging, that predict an intermittent dynamics. For the mechanical
noise the results are unclear. In the polymer the mechanical thermal noise is
still intermittent whereas for the gel the violation of FDT, if it exists, is
extremely small.Comment: to be published in the Proceedings of the XIX Sitges Conference on
''Jammming, Yielding and Irreversible Deformation in Condensed Matter'',
M.-C.Miguel and M. Rubi eds.,Springer Verlag, Berli
Anomalous diffusion and the first passage time problem
We study the distribution of first passage time (FPT) in Levy type of
anomalous diffusion. Using recently formulated fractional Fokker-Planck
equation we obtain three results. (1) We derive an explicit expression for the
FPT distribution in terms of Fox or H-functions when the diffusion has zero
drift. (2) For the nonzero drift case we obtain an analytical expression for
the Laplace transform of the FPT distribution. (3) We express the FPT
distribution in terms of a power series for the case of two absorbing barriers.
The known results for ordinary diffusion (Brownian motion) are obtained as
special cases of our more general results.Comment: 25 pages, 4 figure
Growing Correlation Length on Cooling Below the Onset of Caging in a Simulated Glass-Forming Liquid
We present a calculation of a fourth-order, time-dependent density
correlation function that measures higher-order spatiotemporall correlations of
the density of a liquid. From molecular dynamics simulations of a glass-forming
Lennard-Jones liquid, we find that the characteristic length scale of this
function has a maximum as a function of time which increases steadily beyond
the characteristic length of the static pair correlation function in the
temperature range approaching the mode coupling temperature from above
Jamming at Zero Temperature and Zero Applied Stress: the Epitome of Disorder
We have studied how 2- and 3- dimensional systems made up of particles
interacting with finite range, repulsive potentials jam (i.e., develop a yield
stress in a disordered state) at zero temperature and applied stress. For each
configuration, there is a unique jamming threshold, , at which
particles can no longer avoid each other and the bulk and shear moduli
simultaneously become non-zero. The distribution of values becomes
narrower as the system size increases, so that essentially all configurations
jam at the same in the thermodynamic limit. This packing fraction
corresponds to the previously measured value for random close-packing. In fact,
our results provide a well-defined meaning for "random close-packing" in terms
of the fraction of all phase space with inherent structures that jam. The
jamming threshold, Point J, occurring at zero temperature and applied stress
and at the random close-packing density, has properties reminiscent of an
ordinary critical point. As Point J is approached from higher packing
fractions, power-law scaling is found for many quantities. Moreover, near Point
J, certain quantities no longer self-average, suggesting the existence of a
length scale that diverges at J. However, Point J also differs from an ordinary
critical point: the scaling exponents do not depend on dimension but do depend
on the interparticle potential. Finally, as Point J is approached from high
packing fractions, the density of vibrational states develops a large excess of
low-frequency modes. All of these results suggest that Point J may control
behavior in its vicinity-perhaps even at the glass transition.Comment: 21 pages, 20 figure
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